The Bayern Munich striker, aged 31, has scored an impressive 66 goals in 99 appearances for England since making his debut in 2015. He has now become the first player to reach 100 caps for the England men's team since Wayne Rooney achieved the milestone in November 2014.
"The FA will pay tribute before the UEFA Nations League fixture with a special pre-match ceremony that will include the presentation of a gold cap," the governing body said in a statement.
Before kick-off, the FA will also pay tribute to former England manager Sven-Goran Eriksson, who died at the age of 76 last month.